Anchoring IrPdAu Nanoparticles on NH₂-SBA-15 for Fast Hydrogen Production from Formic Acid at Room Temperature

Hydrogen (H₂), a regenerable and promising energy carrier, acts as an essential role in the construction of a sustainable energy system. Formic acid (HCOOH, FA), a natural biological metabolic products and also accessible through carbon dioxide (CO₂) reduction, has a great potential to serve as a prospective H₂ supplier for the fuel cell. Herein, ultrafine and electron-rich IrPdAu alloy nanoparticles with a size of 1.4 nm are highly dispersed on amine-modified mesoporous SiO₂ (NH₂-SBA-15) and used as a highly active and selective catalyst for fast H₂ production from FA. The as-synthesized IrPdAu/NH₂-SBA-15 possesses superior catalytic activity and 100% H₂ selectivity with initial turnover frequency values of 6316 h^-1 with the additive of sodium formate (SF) and 4737 h^-1 even without SF at 298 K, comparable to the most effective heterogeneous catalysts ever published. The excellent performance of IrPdAu/NH₂-SBA-15 was not only ascribed to the combination of the electronic synergistic effect of trimetallic alloys and the strong metal-support interaction effect but also attributed to the amine (-NH₂) alkaline groups grafted on SBA-15, which is beneficial to boost the split of the O-H bond of FA.