Simultaneous detection of trace Ag(I) and Cu(II) ions using homoepitaxially grown GaN micropillar electrode

Driven by the motivation to quantitively control and monitor trace metal ions in water, the development of environmental-friendly electrodes with superior detection sensitivity is extremely important. In this work, we report the design of a stable, ultrasensitive and biocompatible electrode for the detection of trace Ag⁺ and Cu²⁺ ions by growing n-type GaN micropillars on conductive p-type GaN substrate. The electrochemical measurement based on cyclic voltammetry indicates that the GaN micropillars exhibit quasi-reversible and mass-controlled reaction in redox probe solution. In the application of trace Ag⁺ and Cu²⁺ determination, the GaN micropillars show superior sensitivity and excellent conductivity by presenting a detection limit of 3.3 ppb for Ag⁺ and 3.3 ppb for Cu²⁺. Comparative studies on the electrochemical response of GaN micropillars and GaN film in the simultaneous Ag⁺ and Cu²⁺ detection reveal that GaN micropillars show three orders of magnitude higher stripping peak current than GaN film. It is assumed that the microarray morphology with large active area and the hydrophilia nature of GaN micropillars are responsible for the excellent sensitivity. This work will open up some opportunities for GaN nanostructure electrodes in the application of trace metal ions detection.