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Updated: Dec 29, 2025

Combined Size and Density Fractionation of Soils for Investigations of Organo-Mineral Interactions
Published on: February 15, 2019
Impact of origin and structure on the aggregation behavior of natural organic matter
Peiyun Wei1, Fanchao Xu1, Heyun Fu1
1State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu, 210023, China.
Abstract:
The intermolecular interactions of natural organic matter (NOM) play a key role in the fate and transport of organic carbon and pollutants in environmental and engineered systems. In this study, the impact of origin and structure on the aggregation behavior of NOM was investigated in the presence of naturally abundant cations. The physicochemical properties of NOM were quantified using a range of indices. Thermodynamic analysis suggests that the colloidal stability of NOM was mainly determined by its hydrophobicity (i.e., Lewis acid-base interactions). All NOM can be coagulated by Ca2+ owing to the strong cation-NOM interactions, which lead to bridging effect and lower Lewis acid-base interactions. Terrestrial NOM can be coagulated by Mg2+ while aquatic NOM cannot, owing to their different hydrophobicity. The critical coagulation concentrations of tested terrestrial NOM in the presence of Ca2+ (CCC-Ca) were quite similar at 1.94-4.88 mM despite their different structural properties. The CCC-Ca of tested aquatic NOM varied significantly from 46.89 mM to 110.40 mM depending on their structure. The optical indices including E2/E3, FI, and HIX can be potentially used as convenient indicators for assessing the colloidal stability of aquatic NOM for water treatment and risk assessment purposes.
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