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Published on: August 2, 2019
Precise absolute Seebeck coefficient measurement and uncertainty analysis using high-Tc superconductors as a
Y Amagai1, T Shimazaki1, K Okawa1
1National Institute of Advanced Industrial Science and Technology (AIST), National Metrology Institute of Japan (NMIJ), Tsukuba 305-8563, Japan.
High-temperature superconductors like YBCO and Bi-2223 serve as reliable references for precise Seebeck coefficient measurements of platinum at low temperatures. This study validates their use up to liquid nitrogen temperatures.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Thermodynamics
Background:
- The Seebeck effect, crucial for thermoelectric applications, is challenging to measure absolutely at low temperatures.
- Superconductors, exhibiting unique properties like the Meissner effect, offer potential as precise measurement references.
- High-Tc superconductors, such as YBCO and Bi-2223, are particularly interesting due to their higher critical temperatures.
Purpose of the Study:
- To perform a precision absolute Seebeck coefficient measurement of a platinum sample.
- To validate the use of high-Tc superconductors (YBCO and Bi-2223) as reliable references for these measurements.
- To analyze the uncertainties associated with the measurement technique.
Main Methods:
- Development of a stable cryostat system for precise temperature control.
- Utilizing YBCO as a reference superconductor for absolute Seebeck coefficient determination.
- Comparison of measurements using Bi-2223 as an alternative high-Tc reference.
- Detailed uncertainty analysis focusing on temperature sensing and noise.
Main Results:
- A precision measurement of the Seebeck coefficient for platinum yielded S = 5.6 ± 0.2 µV/K at 80 K, with a 3% relative expanded uncertainty.
- No significant difference was observed between Seebeck coefficient values obtained using YBCO and Bi-2223 references, within measurement uncertainties.
- The primary sources of uncertainty were identified as temperature difference measurements and analog noise.
Conclusions:
- High-Tc superconductors (YBCO and Bi-2223) are validated as effective and reliable references for absolute Seebeck coefficient measurements up to liquid nitrogen temperatures.
- The developed cryostat system and measurement methodology enable accurate thermoelectric property determination.
- This work contributes to the advancement of low-temperature thermoelectric measurements and material characterization.
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