Degradation of dimethyl phthalate using persulfate activated by UV and ferrous ions: optimizing operational...

The present study aimed to model and optimize the dimethyl phthalate (DMP) degradation from aqueous solution using UV_C/ Na₂S₂O₈/Fe²⁺ system based on the response surface methodology (RSM). A high removal efficiency (97%) and TOC reduction (64.2%) were obtained under optimum conditions i.e. contact time = 90 min, SPS concentration = 0.601 mM/L, Fe²⁺ = 0.075 mM/L, pH = 11 and DMP concentration = 5 mg/L. Quenching experiments confirmed that sulfate radicals were predominant radical species for DMP degradation. The effect of CO₃ ^- on DMP degradation was more complicated than other aquatic background anions. The possible pathway for DMP decomposition was proposed according to HPLC and GC-MS analysis. The average oxidation state (AOS) and carbon oxidation state (COS) values as biodegradability indicators demonstrated that the UV_C/SPS/Fe²⁺ system can improve the bioavailability of DMP over the time. Finally, the performance of UV_C/SPS/Fe²⁺ system for DMP treatment in different aquatic solutions: tap water, surface runoff, treated and raw wastewater were found to be 95.7, 88.5, 80.5, and 56.4%, respectively. Graphical abstract.