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Problem Solving on Stress and Strain01:22

Problem Solving on Stress and Strain

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Stress is a quantity that describes the magnitude of a force that causes deformation, generally defined as internal force per unit area. When forces pull on an object and cause its elongation, like the stretching of an elastic band, it is called tensile stress. When forces cause the compression of an object, it is known as compressive stress. When an object is being squeezed uniformly from all sides, like a submarine in the depths of the ocean, we call this kind of stress bulk stress (or volume...
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Colloids and Suspensions01:17

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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Elastic Strain Energy for Shearing Stresses01:20

Elastic Strain Energy for Shearing Stresses

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As discussed in previous lessons, strain energy in a material is the energy stored when it is elastically deformed, a concept crucial in materials science and mechanical engineering. This energy results from the internal work done against the cohesive forces within the material. When a material undergoes shearing stress and corresponding shearing strain, the strain energy density, which is the energy stored per unit volume, is calculated. Within the elastic limit, where the stress is...
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Colloids03:22

Colloids

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Colloidal precipitates01:09

Colloidal precipitates

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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Shearing Strain01:20

Shearing Strain

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The shearing strain represents a cubic element's angular change when subjected to shearing stress. This type of stress can transform a cube into an oblique parallelepiped without influencing normal strains. The cubic element experiences a significant transformation when exposed solely to shearing stress. Its shape alters from a perfect cube into a rhomboid, clearly demonstrating the effect of shearing strain. The degree of this strain is considered positive if it reduces the angle between the...
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Related Experiment Video

Updated: Dec 28, 2025

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
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Viscoelastic cluster densification in sheared colloidal gels.

Roberta Massaro1, Gabriele Colombo, Peter Van Puyvelde

  • 1Department of Chemical Engineering, KU Leuven, Celestijnenlaan 200f, 3001 Heverlee, Belgium.

Soft Matter
|February 11, 2020
PubMed
Summary

This study reveals that fluid viscoelasticity enhances aggregate densification in colloidal suspensions, leading to lower high-shear viscosities. This understanding aids in developing stronger soft matter composites by controlling processing history and medium rheology.

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Area of Science:

  • Soft Matter Physics
  • Colloidal Science
  • Rheology

Background:

  • Colloidal suspensions in complex fluids are ubiquitous in biological, consumer, and industrial applications, acting as soft matter composites.
  • Particle interactions at rest are driven by microstructure distortion, while flow introduces non-Newtonian and viscoelastic effects from the suspending medium.
  • Limited knowledge exists regarding structural evolution, rheology, and final properties of these complex materials under flow.

Purpose of the Study:

  • To investigate the structural development and rheological behavior of a model flocculated suspension in both Newtonian and viscoelastic media.
  • To elucidate the impact of fluid viscoelasticity on aggregate formation, flow properties, and post-shear recovery.
  • To compare the effects of linear versus branched polymers as suspending media.

Main Methods:

  • Utilized combined rheological and rheo-confocal microscopy techniques.
  • Employed micrometer-sized fluorescent PMMA particles dispersed in PDMS polymeric matrices.
  • Conducted stress jump experiments and fast structured illumination confocal microscopy with a counter-rotating rheometer.

Main Results:

  • At comparable interaction strengths (equal Bingham numbers), viscoelastic media promote enhanced aggregate densification during steady-state flow.
  • This densification results in lower limiting high-shear viscosities compared to Newtonian suspensions.
  • Post-shear structural and mechanical recovery is altered, showing an increased percolation threshold in viscoelastic matrices.

Conclusions:

  • Fluid viscoelasticity significantly influences the microstructure and rheology of colloidal suspensions.
  • The findings suggest potential for creating stronger soft matter materials by leveraging processing history and medium rheology at higher particle concentrations.
  • Understanding these complex interactions is crucial for designing and optimizing advanced material formulations.