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Updated: Dec 28, 2025

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
Published on: February 27, 2017
Preparation of nitrogen-containing carbon using a one-step thermal polymerization method for activation of
Wanlin Xue1, Shihai Cao1, Rui Liu2
1Key Laboratory of Jiangsu Province for Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing, 210094, PR China.
Abstract:
Nitrogen-containing carbon materials (NCC-x) are promising metal-free catalysts for activation of peroxymonosulfate (PMS) to treat with aqueous organic pollutants. In this study, NCC-x were synthesized via a facile thermal polymerization method using urea and terephthalaldehyde as precursors. This method was derived from the polymerization method of graphitic carbon nitride (g-C3N4) and the reaction between the precursors was based on Schiff base chemistry. Compared with the synthesis of g-C3N4 using urea as the precursor, formation of a melamine ring was inhibited and the cyano groups were produced in NCC-x during the polymerization process. The obtained NCC-x catalysts had high specific surface areas, many graphite-nitrogen active sites, and high degrees of graphitization, thus exhibiting excellent activities for the degradation of bisphenol A via PMS activation. This study introduces a convenient method to obtain a highly efficient nitrogen-containing carbon PMS activator and the results are useful for the development of bisphenol A treatment by PMS activation using carbon-containing materials.
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