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Updated: Dec 28, 2025

Experimental Study of the Relationship Between Particle Size and Methane Sorption Capacity in Shale
Published on: August 2, 2018
Evaluating Methane Adsorption Characteristics of Coal-Like Materials
Pengxiang Zhao1,2, Hui Liu1, Chun-Hsing Ho3
1College of Safety Science and Engineering, Xi'an University of Science & Technology, Xi'an 710054, China.
Silica gel and activated alumina show promise as coal-like methane adsorption materials. Silica gel is preferred due to its closer methane adsorption coefficient to coal samples in solid-gas coupling experiments.
Area of Science:
- Geochemistry
- Materials Science
- Chemical Engineering
Background:
- Investigating methane adsorption in coal seams is crucial for resource extraction and safety.
- Solid-gas coupling experiments require suitable surrogate materials for coal.
Purpose of the Study:
- To evaluate activated alumina, silica gel, and molecular sieves as potential methane adsorption materials.
- To compare their adsorption characteristics with actual coal samples under various conditions.
Main Methods:
- Methane adsorption experiments were conducted using a WY-98A instrument.
- Tests varied temperature, particle size, and moisture content.
- Adsorption data was analyzed against the Langmuir model and coal sample behavior.
Main Results:
- Molecular sieves did not fit the Langmuir model and were unsuitable.
- Activated alumina and silica gel exhibited similar adsorption trends to coal.
- Silica gel's methane adsorption coefficient closely matched that of coal samples.
Conclusions:
- Silica gel is the preferred material for simulating coal in methane adsorption studies.
- Findings provide an experimental basis for selecting methane-adsorbing materials for physical simulation.
- This research supports the development of solid-gas coupling experiments.
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