High-level waste activated sludge dewaterability using Fenton-like process based on pretreated zero valent scrap iron...

A novel, recyclable, and rapid pre-ultrasound-thermal-acid-washed zero valent scrap iron/hydrogen peroxide (UTA-ZVSI/H₂O₂) method has been developed to effectively enhance waste activated sludge (WAS) dewaterability. The effects of UTA ultrasound densities, UTA temperature, newly generated iron solution, H₂O₂ concentrations, and WAS conditioning time on the WAS dewaterability were investigated using a bench-scale system. Results indicated that the UTA-ZVSI/H₂O₂ treatment significantly improved the WAS dewaterability. The water content of the dewatered cake decreased to 44.15 ± 0.98 wt% during optimal operational conditions, which was significantly lower than that achieved using Fenton-based processes. Based on this outcome, a three-step treatment mechanism involving UTA-ZVSI/H₂O₂ has been developed, including iron flocculation, hydroxyl radical oxidation, and skeleton building. The dewatering efficiencies of three types of representative WAS were consistently effective in the UTA-ZVSI/H₂O₂ reactor for up to 15 cycles. Efficiencies levels were significantly higher than those achieved with Fenton-based processes. Economic analysis illustrated that the developed UTA-ZVSI/H₂O₂ system was the most cost-effective among other WAS dewatering treatments. In addition, the treatment system significantly alleviated toxicity of heavy metals and phytotoxicity in the dewatered sludge. This supported subsequent agricultural use. In summary, this study provided a comprehensive and useful basis for improving WAS dewatering and subsequent disposal.