Multifunctional Inorganic Nanomaterial Aerogel Assembled into fSWNT Hydrogel Platform for Ultraselective NO₂ Sensing

Facile fabrication of multifunctional porous inorganic aerogels remains an outstanding challenge despite the considerable demand for extensive applications. Here, we present the production of a multifunctional porous inorganic nanomaterial aerogel by controllable surface chemistry of a functionalized SWNT (fSWNT) hydrogel platform for the first time. The versatile functional inorganic nanoparticles can be incorporated uniformly on the porous 3D fSWNT hydrogel platform through a facile dip coating method at ambient conditions. The morphology of the multifunctional inorganic aerogel is manipulated by designing the fSWNT hydrogel platform for different requirements of applications. In particular, Pt-SnO₂@fSWNT aerogels exhibit high porosity and uniformly distributed ultrafine Pt and SnO₂ on the fSWNT platform with controllable particle size (1.5-3.5 nm), which result in significantly high surface area (393 m² g^-1). The ultrafine Pt-SnO₂@fSWNT aerogels exhibit highly sensitive (14.77% at 5 ppm) and selective NO₂ sensing performance even at room temperature due to the increased active surface area and controllable porous structure of the ultrafine aerogel, which can provide fast transport and penetration of a target gas into the sensing layers. The newly designed multifunctional inorganic aerogel with ultrahigh surface area and high open porosity is a prospective materials platform of high performance gas sensors, which could be also broadly expanded to widespread applications including catalysis and energy storages.