Label-free, sensitive colorimetric detection of mercury(II) by target-disturbed in situ seeding growth of gold...

Gold nanomaterials have been used extensively in colorimetric detection of mercuric ions (Hg²⁺) due to their shape- and size-dependent, ultrastrong localized surface plasmon resonance (LSPR). Conventional detection was performed by first synthesizing the nanomaterials, and then applying them to signal-transducing reactions. We herein report a convenient method for detecting Hg²⁺ based on gold triangular nanoprisms (AuTNPs). During the seeding-growth process, Hg²⁺ added to the growth solution was co-reduced and deposited on the high-energy facets of the gold seeds, affecting the deposition patterns of the subsequently generated Au⁰ and ultimately leading to the formation of defective AuTNPs. Morphological changes were reflected by the in-plane dipole LSPR wavelength shift, which was proportionally related to the concentration of Hg²⁺. To improve the selectivity, the interference from Ag⁺ was eliminated by a stepwise preparation-selective precipitation approach. Under the optimized conditions, Hg²⁺ could be selectively detected with 20 min, with a detection limit of 0.12 nM. Finally, the method was successfully applied to detecting trace Hg²⁺ in fortified drinking, mineral and rain water samples, with recoveries ranging from 95.17% to 110.6%.