A nanostructured MoO₂/MoS₂/MoP heterojunction electrocatalyst for the hydrogen evolution reaction

Electrocatalytic production of hydrogen from water is considered to be a promising and sustainable strategy. In this work, the low-cost nanostructured MoO₂/MoS₂/MoP heterojunction is successfully synthesized by phosphorization of the pre-prepared urchin-like MoO₂/MoS₂ nanospheres as the stable, highly efficient electrocatalysis for the hydrogen evolution reaction (HER). The MoO₂/MoS₂/MoP-800 (MoO₂/MoS₂ nanospheres are phosphated at 800 °C) displays a catalytic ability for the HER with an overpotential of 135 mV to achieve 10 mA cm^-2 and a Tafel slope of 67 mV dec^-1 in 0.5 M H₂SO₄, which is superior to MoO₂/MoS₂ nanospheres (200 °C; 24 h), MoO₂/MoS₂/MoP-700 (MoO₂/MoS₂ nanospheres are phosphated at 700 °C) and MoO₂/MoS₂/MoP-900 (MoO₂/MoS₂ nanospheres are phosphated at 900 °C). Meanwhile, the catalyst exhibits superior properties for HER with an overpotential of 145 mV to achieve 10 mA cm^-2 and a Tafel slope of 71 mV dec^-1 in 1 M KOH solution. Detailed characterizations reveal that the improved HER performances are significantly related to P-doping and the spherical nanostructure. This work not only provides a low-cost selective for electrocatalytic production of hydrogen, but also serves as a guide to optimize the composition and structure of nanocomposites.