Adsorption anomalies in a two-dimensional model of cluster-forming systems

Adsorption on a boundary line confining a monolayer of particles self-assembling into clusters is studied by Monte Carlo simulations. We focus on a system of particles interacting via competing interaction potential in which effectively short-range attraction is followed by long-range repulsion. For the chemical potential values below the order-disorder phase transition the adsorption isotherms were shown to undergo nonstandard behavior, i.e., the adsorption exhibits a maximum on structural transition between structureless and disordered cluster fluid. In particular, we have found that the adsorption decreases for increasing chemical potential when (i) clusters dominate over monomers in the bulk, (ii) the density profile in the direction perpendicular to the confining line exhibits an oscillatory decay, and (iii) the correlation function in the layer near the adsorption wall exhibits an oscillatory decay in the direction parallel to this wall. Our report indicates striking differences between simple and complex fluid adsorption processes.