Highly Tunable Emission by Halide Engineering in Lead-Free Perovskite-Derivative Nanocrystals: The Cs₂SnX₆ (X = Cl,...

Nanocrystals of Cs₂SnX₆ (X = Cl, Br, Br_0.5I_0.5, and I) have been prepared by a simple, optimized, hot-injection method, reporting for the first time the synthesis of Cs₂SnCl₆, Cs₂SnBr₆, and mixed Cs₂Sn(I_0.5Br_0.5)₆ nanocrystalline samples. They all show a cubic crystal structure with a linear scaling of lattice parameter by changing the halide size. The prepared nanocrystals have spherical shape with average size from 3 to 6 nm depending on the nature of the halide and span an emission range from 444 nm (Cs₂SnCl₆) to 790 nm (Cs₂SnI₆) with a further modulation provided by mixed Br/I systems.