Distribution of uranium and thorium chains radionuclides in different fractions of phosphogypsum grains

This work presents results obtained using gamma spectrometry measurements of phosphogypsum samples on a non-fractionated (native) and fractionated phosphogypsum byproduct. The phosphogypsum was divided into particles size fractions within the range of < 0.063, 0.063-0.090, 0.090-0.125, 0.125-0.250, and over 0.250 mm and analyzed after reaching radioactive equilibrium using high-resolution gamma spectrometry technique. It was found that there is no significant differentiation between ²²⁶Ra distribution among particular grain size fractions of this material; however, tendency for preferential retention of radionuclides in particular grain size fractions is observed. The detailed analysis of results revealed that radium is preferentially retained in smaller grain size fractions, whereas lead and thorium in coarse fractions. The results indicate that overall ²²⁶Ra activity concentrations between particular fractions of phosphogypsum vary globally between - 34 and + 47% regarding non-fractionated material, and for ²¹⁰Pb activity concentration, fluctuations are found between - 26 up and + 38%. Presumably, the mechanism of radium incorporation into gypsum phase is based on a sequence of radium bearing sulfate phases formation followed by a surface adsorption of these phases on the calcium sulfate crystals, whereas for lead and thorium ions, rather incorporation into crystal lattice should be expected as more likelihood process.