Low-temperature catalytic aqueous phase oxidation of microcystin-LR with iron-doped TiO₂ pillared clay catalysts

TiO₂-PILCs and iron-doped TiO₂-PILCs were employed in order to destroy toxic microcystin-LR in the presence of H₂O₂ under the UV light. While less than 5% of the initial microcystin-LR and TOC disappeared in 240 min with the TiO₂-PILCs, almost complete conversion of microcystin-LR could be achieved in 180 min on the 10 wt% iron-doped TiO₂-PILC-A. On the exterior surface of the iron-doped TiO₂-PILCs were mainly located iron particles which had nano-sized diameter and Fe²⁺/Fe³⁺ cations together. Through Fenton-type oxidation on iron particles with H₂O₂, the big microcystin-LR molecules were converted primarily into smaller intermediate organic molecules of hydrocarbons, carboxylic acids and organic amines. The smaller intermediate molecules were believed to be diffused into the pores of the iron-doped TiO₂-PILCs and to be further mineralized into CO₂ and H₂O through the action of photocatalysis on the TiO₂ pillars. However, complete conversion of TOC could not be obtained due to the iron particle deactivation. XPS, TPO and TEM studies showed the continuous accumulation of carbonaceous materials onto the surface of iron particles.