Related Experiment Video
Updated: Dec 27, 2025
Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron
Published on: August 12, 2019
Stereoisomer specific reaction of hexabromocyclododecane with Fe(ii) associated with iron oxides
Xianmiao Zhang1, Kristian K Roopnarine, Shirley Dong
1Chemistry Program, The Graduate Center of the City University of New York, New York, NY 10016, USA.
Abstract:
The reactions of hexabromocyclododecane (HBCD) isomers with Fe(ii) associated with iron oxides were performed in a pH range from 6.15 to 7.50 at room temperature. It was observed that Fe(ii) associated with iron oxides (i.e., goethite, magnetite, hematite) is a better reductant than just an aqueous solution of Fe(ii) to potentially reduce HBCD in subsurface environments. The reaction of HBCD with Fe(ii) associated with iron oxides is also stereoisomer specific with α-HBCD reacting much slower than β-HBCD and γ-HBCD. The reaction is pH dependent and it is faster with increased pH. The initial concentration of Fe(ii) and HBCD can also affect the reaction rate. The reaction is negligible when all the Fe(ii) is sorbed to magnetite and no Fe(ii) remains dissolved. It was also observed that the reaction of 100 nM HBCD is slower than the reaction of 1.0 μM HBCD with Fe(ii) associated with magnetite. In addition, natural organic matter (NOM) was found to inhibit the degradation of HBCD by Fe(ii) associated with iron oxides.
Related Concept Videos
02:44Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
01:17Thermal Electrocyclic Reactions: Stereochemistry
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
02:34Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
01:34Woodward–Hoffmann Selection Rules and Microscopic Reversibility
01:07Structure of Benzene: Kekulé Model
He proposed that benzene has a cyclic structure of six carbon atoms attached to one hydrogen atom each, with three alternating pi bonds.