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'Click' conjugated porous polymer nanofilm with a large domain size created by a liquid/liquid interfacial protocol
Joe Komeda1, Ryo Shiotsuki, Amalia Rapakousiou
1Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Chemical Communications (Cambridge, England)
|March 3, 2020
Abstract:
A liquid/liquid interfacial method is used to synthesize a conjugated porous polymer nanofilm with a large domain size. Copper-catalyzed azide-alkyne cycloaddition between a triangular terminal alkyne and azide monomers at a water/dichloromethane interface generates a 1,2,3-triazole-linked polymer nanofilm featuring a large aspect ratio and robustness against heat and pH.
