Role of phosphate concentration in control for phosphate removal and recovery by layered double hydroxides

Phosphorus removal from wastewater has become urgent because of eutrophication control. Phosphate concentration in control for phosphate removal and recovery by Mg-Fe oxide has been investigated. The results show that the adsorption capacity of phosphate by Mg-Fe oxide calcined at 450 °C was 28.3 mg/g, and it was kept at wide optimal adsorption pH ranges (4-10). The coexisting ions had influenced phosphate adsorption process and the order is CO₃^2- > SO₄^2- > NO₃^- > Cl^-, with the inhibition rate of CO₃^2- being 43%. Interestingly, phosphate concentration plays an important role in phosphate removal by Mg-Fe oxide. Under higher initial phosphate concentrations (200-800 mg/L), Sips model was well fitted. In addition, the adsorption kinetics was well described by the pseudo-second-order kinetic model before 25 min and the pseudo-first-order kinetic model after 25 min. In contrast, Langmuir model and pseudo-second-order kinetic model were fitted under lower initial phosphate concentrations (20-200 mg/L). The results of XRD, XPS, SEM, and TEM characterization show that Mg₃(PO₄)₂ was formed by surface precipitation under 800 mg/L phosphate solution, and Mg-Fe layered structure was present via the unique memory effect under 20 mg/L phosphate solution. Mg-Fe oxide can be recovered through CO₃^2- ion exchange, and the removal efficiency of phosphate was 56% after seven cycles.