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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
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Chemically Functionalized Two-Dimensional Carbon Materials.

Ryo Sekiya1, Takeharu Haino1

  • 1Department of Chemistry Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1, Kagamiyama, Higashi-Hiroshima, Hiroshima, 739-8526, Japan.

Chemistry, an Asian Journal
|March 5, 2020
PubMed
Summary
This summary is machine-generated.

Nanographenes (NGs), or graphene quantum dots, are nanoscale graphene fragments with tunable photoemission properties. Recent advances focus on postsynthetic modification to create advanced carbon-based materials.

Keywords:
chemical functionalizationgraphenegraphene quantum dotnanographenesupramolecular chemistry

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Organic Chemistry

Background:

  • Nanographenes (NGs), also known as graphene quantum dots, are nanoscale graphene fragments.
  • These materials exhibit tunable photoemission properties upon UV excitation, spanning the UV-to-visible spectrum.
  • NGs have garnered significant interest across diverse scientific disciplines due to their unique optical characteristics.

Purpose of the Study:

  • To review recent advancements in the postsynthetic modification of nanographenes.
  • To highlight how modifying NGs with organic groups enhances their properties and functionalities.
  • To provide a concise overview of established nanographene production methods.

Main Methods:

  • Exploration of organic synthesis routes for nanographene production.
  • Investigation of postsynthetic modification strategies for nanographenes.
  • Analysis of literature detailing the functionalization of NGs with organic groups.

Main Results:

  • Postsynthetic modification allows for precise tuning of nanographene properties.
  • Functionalized NGs offer new capabilities, enabling sophisticated carbon-based material development.
  • A growing body of research focuses on enhancing NG performance through chemical modification.

Conclusions:

  • Postsynthetic modification is a key strategy for advancing nanographene applications.
  • Tailoring NGs via organic functionalization unlocks potential in various fields.
  • Continued research in NG modification promises novel functional materials.