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Updated: Dec 27, 2025

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
Published on: February 27, 2017
Olefin Cross Metathesis as a Versatile Method for the Facile Functionalization of Porous Polymers
Amaia Altuna-Ruiz de Eguino1,2, Peter A G Cormack1, Joëlle Prunet2
1WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Thomas Graham Building, 295 Cathedral Street, Glasgow G1 1XL, U.K.
Abstract:
Olefin cross metathesis has been employed for the first time for the postpolymerization chemical modification of porous polymers. High quality microspheres of poly(divinylbenzene) were synthesized by the precipitation polymerization of divinylbenzene-55 in porogenic solvents, and the olefin cross metathesis reactions of the pendent (polymer-bound) vinyl groups not consumed by polymerization were performed with diverse coupling partners in dichloromethane using the Grubbs 2 catalyst, leading to microspheres decorated with a wide range of functional groups.
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