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Related Experiment Video

Updated: Dec 27, 2025

Triplet Fusion Upconversion Nanocapsule Synthesis
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Enhancing multiphoton upconversion through interfacial energy transfer in multilayered nanoparticles.

Bin Zhou1, Bing Tang1, Chuang Zhang2

  • 1State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, 430074, Wuhan, China.

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|March 6, 2020
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Summary

Researchers developed a novel multilayered nanoparticle structure to boost photon upconversion efficiency. This design overcomes concentration quenching, enhancing multiphoton emission for advanced applications like deep-tissue biophotonics.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Photonics

Background:

  • Lanthanide-doped upconversion nanoparticles (UCNPs) are crucial for applications like deep-tissue biophotonics.
  • However, their efficiency, especially for multiphoton emission, is hindered by concentration quenching.

Purpose of the Study:

  • To design and investigate a novel multilayered core-shell-shell UCNP structure.
  • To enhance multiphoton emission by spatially separating activators and sensitizers and suppressing concentration quenching.

Main Methods:

  • Fabrication of a NaYF4 core-shell-shell nanostructure with spatially separated Er3+ activators and Yb3+ sensitizers.
  • Analysis of structural and temperature-dependent multiphoton upconversion luminescence.
  • Quantum yield measurements.

Main Results:

  • A 100-fold enhancement in multiphoton emission from Er3+ was achieved compared to conventional core-shell UCNPs.
  • Efficient excitation energy transfer at the core-shell interface was observed.
  • Suppression of concentration quenching led to a high quantum yield of up to 6.34%.

Conclusions:

  • The multilayered core-shell-shell structure effectively overcomes the limitations of concentration quenching in UCNPs.
  • This design enables significantly enhanced multiphoton emission, paving the way for advanced UCNP applications.
  • The findings offer a versatile strategy for designing next-generation upconverting nanoparticles.