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Updated: Dec 27, 2025
A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
Published on: May 9, 2014
A facile template-free strategy for synthesizing hydroxymethyl-poly(3,4-ethylenedioxythiophene) nanospheres
Chanhyuk Jee1, Kyung Seok Kang1, Ji-Hong Bae1
1Pusan National University, Department of Polymer Science and Engineering, Busan, 609-735, South Korea.
Abstract:
Hydroxymethyl-poly(3,4-ethylenedioxythiophene)(PEDOT-OH) nanospheres self-assembled using physical blowing method, which continually used a syringe, were successfully formed through aqueous solution polymerization under the oxidative initiators. The effect of blowing on the morphological properties of PEDOT-OH was precisely evaluated based on the different amount of initiator. The concentration of ammonium persulfate might be a driving force in the self-assembly process to create the PEDOT-OH nanospheres. The electrical and electrochemical properties of the resulting nanospheres were also characterized using four-point probe and cyclic voltammetry.
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