Magnetite nanoparticles decorated on multi-walled carbon nanotubes for removal of Cu²⁺ from aqueous solution

Acid-functionalized multi-walled carbon nanotube (MWCNTs-COOH) was prepared by acid treatment followed by decoration with magnetite (Fe₃O₄) nanoparticles (Fe₃O₄/MWCNTs-COOH) by co-precipitation of Fe²⁺/Fe³⁺ in the colloidal suspension of MWCNTs-COOH. The adsorption capacity and separation efficiency of these two adsorbents were investigated for the removal of Cu²⁺ ions in aqueous solution as water treatment adsorbents. The effect of reaction conditions, such as contact time, initial concentration of Cu²⁺ ions, and adsorbent dosage, on the adsorption capacity of MWCNTs-COOH was investigated. It was found that contact time of 10 min, adsorbent dosage of 0.2 g/L and 15 mg/L as initial concentration of Cu²⁺ ions are ideal conditions for maximum adsorption capacity (10.45 mg/g). The adsorption capacity of synthesized Fe₃O₄/MWCNTs-COOH containing different weight percent of Fe₃O₄ (10, 25, 50 wt%) was explored for removal of Cu²⁺ ions from aqueous solution and the best results achieved with 25 wt% Fe₃O₄/MWCNTs-COOH, which exhibited optimum adsorption capacity of 9.50 mg/g and 97% separation efficiency. Further, Langmuir and Freundlich isotherm models were applied to validate experimental data obtained in this work for Cu²⁺ adsorption.