2D graphdiyne: an excellent ultraviolet nonlinear absorption material
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Updated: Dec 26, 2025

Graphene-Assisted Quasi-van der Waals Epitaxy of AlN Film on Nano-Patterned Sapphire Substrate for Ultraviolet Light Emitting Diodes
Published on: June 25, 2020
Fang Zhang1, Guowei Liu1, Junjie Yuan1
1School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. yourszhangfang1988@126.com xingfei@sdut.edu.cn.
Abstract:
With an sp2-hybridized carbon atom structure, graphene is recognized as a nonlinear absorption (NLA) material, which has motivated scientists to explore new allotropes of carbon. Different from graphene, graphdiyne (GDY) consists of sp- and sp2-hybridized carbon atoms. An sp-hybridized carbon-carbon triple bond structure will bring in novel nonlinear optical properties, which are different from other allotropes of carbon. In this study, we investigated the broadband NLA properties (ultraviolet-infrared waveband) of GDY nanosheets, exfoliated using a liquid-phase exfoliation (LPE) method. The short ultraviolet cut-off wavelength (around 200 nm-220 nm) forebodes the potential application of GDY as an ultraviolet optical material. The outstanding NLA resulting in an ultraviolet waveband attests that the GDY nanosheets are veritable ultraviolet NLA materials, which have potential applications in ultraviolet optics. Our study broadens the application scopes of nanomaterials.
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