Fabrication of amine functionalized CdSe@SiO₂ nanoparticles as fluorescence nanosensor for highly selective and...

In this work, amino functionalized CdSe-silica core-shell nanoparticles (NH₂-CdSe@SiO₂ NPs) were constructed as probe to detect picric acid (PA). The CdSe QDs were embedded in SiO₂ nanoparticles and modified with amino groups on the surface. The nitro explosives are electron deficient in nature, which will have stronger affinity for amines and resulted in fluorescence quenching of quantum dots. It was proved that this strategy is selective, easy and sensitive enough for sensing PA with a detection limit of 0.5 × 10^-7 M.