Sequential colorimetric sensing of cupric and mercuric ions by regulating the etching process of triangular gold...

A triangular gold nanoplate (AuNPL)-based colorimetric assay is presented for ultrasensitive determination of cupric ions (Cu²⁺⁾ and mercuric ions (Hg²⁺) in sequence. AuNPLs were found to be etched efficiently when producing triiodide ions (I₃^-) by a redox reaction between Cu²⁺ and iodide ions (I^-), leading to a change of the shape of AuNPLs from triangular to sphere along with a color change from blue to pink. In the presence of Hg²⁺ the etching of AuNPLs was suppressed due to the consumption of I^- by the formation of HgI₂. With an increase of the concentration of the Hg²⁺ a transformation from sphere to triangular in the shape of AuNPLs occurred with a color change from pink to blue. The evolution of AuNPLs from etching to anti-etching state by sequential addition of Cu²⁺ and Hg²⁺ was accompanied with color variations and band shifts of localized surface plasmon resonance (LSPR), allowing for visual and spectroscopic determination of Cu²⁺ and Hg²⁺ successively within 15 min. In the range 0.01-1.5 μM for Cu²⁺ and 0.02-3.0 μM for Hg²⁺, the linear relationship between the band shift values and the target ions concentration was found good (R² > 0.996). The limit of detections (3S/k) was 19 nM for Cu²⁺ and 9 nM for Hg²⁺, respectively. The lowest visual estimation concentration was 80 nM for both Cu²⁺ and Hg²⁺ through the distinguishable color changes. This system exhibited desirable selectivity for Cu²⁺ and Hg²⁺ over other common ions tested. The method has been successfully applied to sequential determination of Cu²⁺ and Hg²⁺ in real water and food samples. Graphical abstract Scheme 1 Schematic illustration for sequential detection of Cu²⁺ and Hg²⁺ based on etching of AuNPLs.