UV/Vis Spectroscopy of Copper Formate Clusters: Insight into Metal-Ligand Photochemistry

The electronic structure and photochemistry of copper formate clusters, Cu^I ₂ (HCO₂ )₃ ^- and Cu^II _n (HCO₂ )_2n+1 ^- , n≤8, are investigated in the gas phase by using UV/Vis spectroscopy in combination with quantum chemical calculations. A clear difference in the spectra of clusters with Cu^I and Cu^II copper ions is observed. For the Cu^I species, transitions between copper d and s/p orbitals are recorded. For stoichiometric Cu^II formate clusters, the spectra are dominated by copper d-d transitions and charge-transfer excitations from formate to the vacant copper d orbital. Calculations reveal the existence of several energetically low-lying isomers, and the energetic position of the electronic transitions depends strongly on the specific isomer. The oxidation state of the copper centers governs the photochemistry. In Cu^II (HCO₂ )₃ ^- , fast internal conversion into the electronic ground state is observed, leading to statistical dissociation; for charge-transfer excitations, specific excited-state reaction channels are observed in addition, such as formyloxyl radical loss. In Cu^I ₂ (HCO₂ )₃ ^- , the system relaxes to a local minimum on an excited-state potential-energy surface and might undergo fluorescence or reach a conical intersection to the ground state; in both cases, this provides substantial energy for statistical decomposition. Alternatively, a Cu^II (HCO₂ )₃ Cu^0- biradical structure is formed in the excited state, which gives rise to the photochemical loss of a neutral copper atom.