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From nanoscale interface characterization to sustainable energy storage using all-solid-state batteries.

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Highly conductive solid-state electrolytes (SSEs) advance all-solid-state batteries (ASSBs). This review addresses challenges in interfacial stability, scalability, safety, and sustainable recycling for practical ASSB applications.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid-state electrolytes (SSEs) are key to developing safer, high-performance all-solid-state batteries (ASSBs).
  • Current research often focuses on discovering new SSE materials, overlooking critical practical challenges.
  • Existing ASSBs face limitations including poor interfacial stability, manufacturing scalability, and safety concerns.

Purpose of the Study:

  • To provide a comprehensive review of SSEs beyond conventional metrics like conductivity and chemical stability.
  • To highlight crucial bulk, interface, and nanoscale phenomena requiring scientific attention.
  • To assess current characterization techniques and propose future full-cell ASSB prototyping strategies.

Main Methods:

  • Literature review and critical analysis of existing SSE research.
  • Evaluation of current state-of-the-art characterization techniques for SSEs.
  • Assessment of full-cell ASSB prototyping and recycling strategies.

Main Results:

  • Identified key barriers to ASSB commercialization: interfacial issues, scalability, and safety.
  • Highlighted the need for advanced characterization methods beyond standard conductivity and stability tests.
  • Proposed potential solutions for fundamental obstacles and outlined strategies for sustainable ASSB recycling.

Conclusions:

  • ASSB development requires a holistic approach addressing material discovery, interfacial engineering, and scalable manufacturing.
  • Sustainable recycling models are essential for the long-term viability of ASSB technology.
  • Further research into nanoscale phenomena and advanced characterization is crucial for overcoming current limitations.