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Updated: Dec 26, 2025

Synthesis and Performance Evaluations of ZnCoS/ZnCdS with Twin Crystal Structure for Multifunctional Redox Photocatalysis in Energy Applications
Published on: July 25, 2025
Synergism of photocycloaddition and photoinduced electron transfer for multi-state responsive materials with
Xiao-Dong Yang1, Mei-Jing Ma1, Xin-Zhu Pang2
1MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China. zhangjie68@bit.edu.cn.
Abstract:
A dual-photoresponsive coordination polymer displaying color-distinguishable olefin/cyclobutane-linked pyridinium radical states through photoinduced electron transfer and photocycloaddition has been successfully assembled based on the monoquaternized trans-1,2-bis(4-pyridyl)ethylene and electron-rich benzenetetra-carboxylate anion. The synergy of charge-transfer and cation-π interactions within the framework endows the compound with excellent stability toward high temperature (350 °C), acidic/basic environments (pH = 2-12) and organic solvents. Reversible recovery from the radical states to their initial states, and reverse-cyclization can be achieved upon heat-treatment.
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