Preparation of MWCNT Microbeads for the Application of Bed Materials in a Fluidized Bed Heat Exchanger

Fluidized beds have been utilized for various chemical and physical applications including heat transfer such as the gas-solid heat exchanger. It is advantageous to use carbon nanotubes (CNTs) with high thermal conductivity as bed materials for heat transfer enhancement in a direct gas-solid contacting heat exchanger. However, the poor fluidization of CNTs is the biggest challenge due to the strong cohesive force between the particles. A control over the macroscopic shapes of CNT powders is required for their application. A preparation method of CNT microbeads has been proposed to be suitable for fluidized bed applications. The method is characterized by using m-cresol known as processing solvents for fabrication of the CNT microbeads. Multiwalled CNT powders were directly mixed with m-cresol to yield a thick paste-like material. The paste droplets were rolled into round particles with in pure water with and without surfactant. The obtained particles were dried in a vacuum oven. The obtained microbeads have diameters ranging 300-2200 μm and apparent particle density of 350-400 kg/m³, which corresponds to Geldart group B in the fluidization classification. The micrograph of the CNT microbeads exhibited stacked nanotubes array on the surface, indicating obvious densification of the raw CNT powders. The microbeads prepared in water containing surfactant have better shape factor such as circularity and solidity. The thermal conductivity of the microbeads is about 1.18 W/mK in a bulk state, which is much higher than raw CNT powder (0.032 W/mK). The flowability and fluidization characteristics of the multiwalled CNT (MWCNT) microbeads showed a possibility as promising bed material suitable for the fluidized bed heat exchanger.