Platinum and Iridium Oxide Co-modified TiO₂ Nanotubes Array Based Photoelectrochemical Sensors for Glutathione

Oriented TiO₂ nanotubes, which are fabricated by anodic oxidation method, are prospective in photoelectrochemical analysis and sensors. In this work, Pt and IrO₂ co-modified TiO₂ nanotubes array was prepared via a two-step deposition process involving the photoreductive deposition of Pt and chemical deposition of IrO₂ on the oriented TiO₂ nanotubes. Due to the improved separation of photo-generated electrons and holes, Pt-IrO₂ co-modified TiO₂ nanotubes presented significantly higher PEC activity than pure TiO₂ nanotubes or mono-modified TiO₂ nanotubes. The PEC sensitivity of Pt-IrO₂ co-modified TiO₂ nanotubes for glutathione was also monitored and good sensitivity was observed.