Study on Pollution Characterization and Source Apportionment of Daytime and Nighttime PM_2.5 Samples in an Urban...

Daytime and nighttime PM_2.5 samples were collected from an urban community in Tianjin. The major chemical components in PM_2.5, including metal elements, polycyclic aromatic hydrocarbons and inorganic water-soluble ions, were monitored. A positive matrix factorization (PMF) model was used to apportion the potential sources of PM_2.5 under different weather conditions. When the Air Quality Index (AQI) was below 200, the concentrations of BaA, BbF, BkF, Na and NO₃^- during the nighttime were higher than those during the daytime. PMF analysis indicated that secondary aerosols (37.3%), biomass burning (26.7%) and coal combustion (26.0%) were important sources of PM_2.5 in the urban residential community when the AQI was greater than 200. When the AQI was less than 200 in the urban residential community, the main sources of PM_2.5 in the urban residential community were secondary aerosols (50.7%) and fossil fuel combustion (47.2%). The pollution status of PM_2.5 in the residential community of the urban area was serious, and the source apportionments of the PM_2.5 samples in the urban area were different under different weather conditions.