Enhanced photoelectrocatalytic degradation of bisphenol a by BiVO₄ photoanode coupling with peroxymonosulfate

Peroxymonosulfate (PMS) was introduced into a photoelectrocatalytic (PEC) system with a bismuth vanadate (BiVO₄) photoanode to enhance the PEC oxidation of bisphenol A (BPA). With the addition of 5 mM PMS, the degradation efficiency of 10 mg/L BPA was significantly improved from 24.2% to 100.0% within 120 min and the side reaction of O₂ evolution was avoided at a potential as low as 0.25 V. The electron spin resonance and radicals quenching results suggested that photogenerated holes instead of SO₄^•- and OH were primarily responsible for the BPA degradation. To further explore the role of PMS, a photocatalytic fuel cell with the structure of BiVO₄ (photoanode)|10 mg/L BPA|proton exchange membrane (separator)|5 mM PMS|Pt (cathode) was constructed and demonstrated that PMS played a key role as electrons acceptor instead of the precursor of SO₄^•-. The PEC tests including open-circuit potential, linear sweep voltammetry and electrochemical impedance spectroscopy indicated that a more efficient separation of photogenerated charges was achieved in the PEC process with the help of PMS, thus generating more photogenerated holes for enhanced BPA degradation. This work may provide a novel way to enhance the separation of photogenerated charges at the photoanode.