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Updated: Dec 25, 2025

1,3,5-Triphenylbenzene and Corannulene as Electron Receptors for Lithium Solvated Electron Solutions
Published on: October 10, 2016
Isolation and characterization of a lithiated pyridine - aggregation in the solid state and in solution
Nadja M C Schmidlin1, Harald Scherer1, Anke Hoffmann1
1Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstr. 19, 79104 Freiburg, Germany. tobias.boettcher@ac.uni-freiburg.de.
Abstract:
Pyridyllithiums are ubiquitous intermediates used for the electrophilic functionalization of pyridines. In this work, the isolation of a pyridyllithium is reported. Single crystal XRD revealed a dimer in the solid state. In THF solution it was identified as a monomer using DOSY NMR spectroscopy. Calculations showed that the pyridyllithium is a very electron rich pyridine superbase, which may account for its high reactivity.

