Impact of Pd Loading on CO₂ Reduction Performance over Pd/TiO₂ with H₂ and H₂O

This study investigated the impact of molar ratio of CO₂ to reductants H₂O and H₂, as well as Pd loading weight on CO₂ reduction performance with Pd/TiO₂ as the photocatalyst. The Pd/TiO₂ film photocatalyst is prepared by the sol-gel and dip-coating process to prepare TiO₂ film and the pulse arc plasma method is used to dope Pd on TiO₂ film. The prepared Pd/TiO₂ film was characterized by SEM, EPMA, STEM, EDS, and EELS. This study also investigated the performance of CO₂ reduction under the illumination condition of Xe lamp with or without ultraviolet (UV) light. As a result, it is revealed that when the molar ratio of CO₂/H₂/H₂O is set at 1:0.5:0.5, the best CO₂ reduction performance has been obtained under the illumination condition of Xe lamp with and without UV light. In addition, it is found that the optimum Pd loading weight is 3.90 wt%. The maximum molar quantities of CO and CH₄ produced per unit weight of photocatalyst are 30.3 μmol/g and 22.1 μmol/g, respectively, for the molar ratio of CO₂/H₂/H₂O = 1:0.5:0.5 under the condition of Xe lamp illumination with UV light. With UV light, C₂H₄ and C₂H₆, as well as CO and CH₄ are also produced by the Pd/TiO₂ film photocatalyst prepared in this study.