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Synthesis and characterization of cyclodextrin-based acrylamide polymer flocculant for adsorbing water-soluble dyes
Qiong Su1,2, Yuxing Wang1,2, Wanhong Sun2,3
1College of Chemical Engineering, Northwest Minzu University, Lanzhou 730030, People's Republic of China.
Abstract:
A novel hydrophobic and cationic cyclodextrin-based acrylamide flocculant (AM-β-CD-DMDAAC) was prepared by chemical oxidative polymerization to adsorb water-soluble dyes in dye wastewater. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscope and thermogravimetric (TG) measurements results demonstrated that the AM-β-CD-DMDAAC was successfully synthesized. The effects of pH, contact time, initial dye concentration, temperature and adsorbent dose on dye removal efficiency for AM-β-CD-DMDAAC flocculants were investigated. The kinetic data were found to follow the pseudo-second-order kinetic model. The equilibrium adsorption data were fitted to the Langmuir isotherm model, with the maximum adsorption capacity of 147.1 mg g-1. The adsorbent retained about 60% of the adsorption efficiency after three adsorption/desorption cycles, which implied a promising application as the dye adsorbent.
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