Sustainable hydrogen production by molybdenum carbide-based efficient photocatalysts: From properties to mechanism

Hydrogen is considered to be a promising energy carrier to solve the issue of energy crisis. Molybdenum carbide (Mo_xC) is the typical material, which has similar properties of Pt and thought to be an attractive alternative to noble metals for H₂ evolution. The study of Mo_xC as alternative catalyst for H₂ production is almost focused on electrocatalytic field, while the application of Mo_xC as a co-catalyst in photocatalytic H₂ evolution has received in-depth research in recent years. Particularly, Mo_xC exhibits significant enhancement in the H₂ production performance of semiconductors under visible light irradiation. However, a review discussing Mo_xC serving as a co-catalysts in the photocatalytic H₂ evolution is still absent. Herein, the recent progress of Mo_xC on photocatalytic H₂ evolution is reviewed. Firstly, the preparation methods including chemical vapor deposition, temperature programming, and organic-inorganic hybridization are detailly summarized. Then, the fundamental structure, electronic properties, and specific conductance of Mo_xC are illustrated to illuminate the advantages of Mo_xC as a co-catalyst for H₂ evolution. Furthermore, the different heterojunctions formed between Mo_xC and other semiconductors for enhancing the photocatalytic performance are emphasized. Finally, perspectives regarding the current challenges and the future research directions on the improvement of catalytic performance of Mo_xC-based photocatalysts are also presented.