Investigation of the transit-time broadening in optical nanofiber based spectroscopy

Optical nanofiber is a widely adopted platform for highly efficient light-matter interaction by virtue of its exposed evanescent field with high light intensity. However, the strongly constrained mode field with the wavelength-scale size makes the light-matter interaction time limited in consideration of the random thermal motion of warm molecules, which results in considerable transit-time dephasing and thus line broadening. Here we report a systematic study of the transit-time effect associated with the optical nanofibers. Both simulation and experiment for nanofibers exposed in acetylene demonstrate the considerable transit-time broadened linewidth in the low-pressure range.