Optimization of Boron Doped TiO₂ as an Efficient Visible Light-Driven Photocatalyst for Organic Dye Degradation With...

No visible light activity is the bottle neck for wide application of TiO₂, and Boron doping is one of the effective way to broaden the adsorption edge of TiO₂. In this study, several Boron doped TiO₂ materials were prepared via a facile co-precipitation and calcination process. The B doping amounts were optimized by the degradation of rhodamine B (Rh B) under visible light irradiation, which indicated that when the mass fraction of boron is 6% (denoted as 6B-TiO₂), the boron doped TiO₂ materials exhibited the highest activity. In order to investigate the enhanced mechanism, the difference between B-doped TiO₂ and bare TiO₂ including visible light harvesting abilities, separation efficiencies of photo-generated electron-hole pairs, photo-induced electrons generation abilities, photo-induced charges transferring speed were studied and compared in details. h⁺ and ^· $$ were determined to be the two main responsible active species in the photocatalytic oxidation process. Besides the high degradation efficiency, 6B-TiO₂ also exhibited high reusability in the photocatalysis, which could be reused at least 5 cycles with almost no active reduction. The results indicate that 6B-TiO₂ has high photocatalytic degradation ability toward organic dye of rhodamine B under visible light irradiation, which is a highly potential photocatalyst to cope with organic pollution.