Capsules of Reactive Ionic Liquids for Selective Capture of Carbon Dioxide at Low Concentrations

The task-specific ionic liquid (IL), 1-ethyl-3-methylimidazolium 2-cyanopyrolide ([EMIM][2-CNpyr]), was encapsulated with polyurea (PU) and graphene oxide (GO) sheets via a one-pot Pickering emulsion, and these capsules were used to scrub CO₂ (0-5000 ppm) from moist air. Up to 60 wt % of IL was achieved in the synthesized capsules, and we demonstrated comparable gravimetric CO₂ capacities to zeolites and enhanced absorption rates compared to those of bulk IL due to the increased gas/liquid surface-to-volume area. The reactive IL capsules show recyclability upon mild temperature increase compared to zeolites that are the conventional absorber materials for CO₂ scrubbing. The measured breakthrough curves in a fixed bed under 100% relative humidity establish the utility of reactive IL capsules as moisture-stable scrubber materials to separate CO₂ from air, outperforming zeolites owing to their higher selectivity. It is shown that thermal stability, CO₂ absorption capacity, and rate of uptake by IL capsules can be further modulated by incorporating low-viscosity and nonreactive ILs to the capsule core. This study demonstrates an alternative and facile approach for CO₂ scrubbing, where separation from gas mixtures with extremely low partial pressures of CO₂ is required.