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Temperature expansions in the square-shoulder fluid. I. The Wiener-Hopf function
1Institut für Materialphysik im Weltraum, Deutsches Zentrum für Luft- und Raumfahrt (DLR), 51170 Köln, Germany.
Abstract:
We investigate the spatial structure of dense square-shoulder fluids. To this end, we derive analytical perturbative solutions of the Ornstein-Zernike equation in the low- and high-temperature limits as expansions around the known hard sphere solutions. We then discuss the suitability of perturbative approaches in relation to the Ornstein-Zernike equation. Our analytical expressions are shown to reproduce reasonably well numerical data in the appropriate regimes.
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