Enhanced Emission of Zinc Nitride Colloidal Nanoparticles with Organic Dyes for Optical Sensors and Imaging...

Herein, we have reported on the efficiency of inorganic Zn₃N₂ nanoparticles for labeling plant cells and animal cells toward imaging applications with negligible toxicity. We have synthesized zinc nitride (Zn₃N₂) colloidal nanoparticles with an average size of 25 nm at room temperature. The optical band gap of the prepared Zn₃N₂ nanoparticles is 2.8 eV and gives a visible range emission at 415 nm. With the addition of Zn₃N₂ colloids to organic dyes such as protoporphyrin, flavin adenine dinucleotide, fluorescein, and neutral red, the emission intensity of the organic dyes enhanced from 3 to 20 times. The molecular simulation and lifetime studies evidence the possibility of energy transfer from zinc nitride to organic dyes. The enhancement of dye intensity in the presence of Zn₃N₂ enhanced the vicinity of the cellular environment during confocal imaging of plant cells and animal cells. The detailed results suggested Zn₃N₂ for bioimaging and biosensor applications.