Low-Temperature Carbon Dioxide Gas Sensor Based on Yolk-Shell Ceria Nanospheres

Monitoring carbon dioxide (CO₂) levels is extremely important in a wide range of applications. Although metal oxide-based chemoresistive sensors have emerged as a promising approach for CO₂ detection, the development of efficient CO₂ sensors at low temperature remains a challenge. Herein, we report a low-temperature hollow nanostructured CeO₂-based sensor for CO₂ detection. We monitor the changes in the electrical resistance after CO₂ pulses in a relative humidity of 70% and show the high performance of the sensor at 100 °C. The yolk-shell nanospheres have not only 2 times higher sensitivity but also significantly increased stability and reversibility, faster response times, and greater CO₂ adsorption capacity than commercial ceria nanoparticles. The improvements in the CO₂ sensing performance are attributed to hollow and porous structure of the yolk-shell nanoparticles, allowing for enhanced gas diffusion and high specific surface area. We present an easy strategy to enhance the electrical and sensing properties of metal oxides at a low operating temperature that is desirable for practical applications of CO₂ sensors.