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Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
Three-dimensionally macroporous MnZrOx catalysts for propane combustion: Synergistic structure and doping effects on
Kai Zeng1, Xingyun Li1, Chao Wang2
1Institute of Materials for Energy and Environment, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, PR China.
Abstract:
Three-dimensionally macroporous (3DM) MnZrOx catalysts were fabricated to reveal the structure and Zr-doping effects on both physicochemical properties and propane combustion behaviors. The increasing addition of zirconium is favorable for the formation of 3DM structure and amorphous Mn-Zr solid solution, leading to tunable physicochemical properties. The significant activity improvement after zirconium addition was originally attributable to the superior redox ability, higher oxygen mobility and more abundant oxygen vacancy. The excellent catalytic activity, cycling stability and water resistant ability over 3DM Mn0.6Zr0.4Ox make it a promising material for hydrocarbons elimination. The comparative TPSR, in situ DRIFTs and kinetics study over 3DM and bulk catalysts emphasize the advantageous function of 3DM architecture on promoting propane adsorption, oxidation and lattice oxygen mobility.
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