Performance and energetic analysis of hydrodynamic cavitation and potential integration with existing advanced...

The current work is a "first of a kind" report on the feasibility and efficacy of hydrodynamic cavitation integrated Advanced Oxidation Processes (AOP's) towards treatment of a real life greywater stream in form of kitchen wastewater. The work has been carried out in a sequential manner starting with geometry optimization of orifice plate (cavitating device) followed by studying the effects of inlet pressure, pH, effluent dilution ratio on degradation of TOC and COD. Under optimized conditions of pH 3, 4 bar pressure, TOC and COD reduction of 18.23 and 25% were obtained using HC for a period of 120 min. To improve the performance of HC, further studies were carried out by integrating H₂O₂and O₃with HC. Using 5 g/h optimum dosage of H₂O₂, 87.5% reduction in COD was obtained beyond which it started decreasing. Moreover, integrating O₃(57.5% reduction in COD) increased the treatment cost. However, a hybrid process (HC + H₂O₂ + O₃) yielded 76.26 and 98.25% reductions in TOC and COD within60 min.The energetics of all the processes and the treatment costs were studied in detail and it was concluded that combined process of HC + H₂O₂ + O₃surpassed by far the performances of HC + H₂O₂and HC + O₃.