Tin and Tin Compound Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review

Tin and tin compounds are perceived as promising next-generation lithium (sodium)-ion batteries anodes because of their high theoretical capacity, low cost and proper working potentials. However, their practical applications are severely hampered by huge volume changes during Li⁺ (Na⁺) insertion and extraction processes, which could lead to a vast irreversible capacity loss and short cycle life. The significance of morphology design and synergic effects-through combining compatible compounds and/or metals together-on electrochemical properties are analyzed to circumvent these problems. In this review, recent progress and understanding of tin and tin compounds used in lithium (sodium)-ion batteries have been summarized and related approaches to optimize electrochemical performance are also pointed out. Superiorities and intrinsic flaws of the above-mentioned materials that can affect electrochemical performance are discussed, aiming to provide a comprehensive understanding of tin and tin compounds in lithium(sodium)-ion batteries.