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Updated: Dec 24, 2025
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
A redetermination of the crystal structure of the mannitol complex NH4[Mo2O5(C6H11O6)]·H2O: hydrogen-bonding scheme
Masoud Mirzaei1, Morteza Tahmasebi1, Joel T Mague2
1Department of Chemistry, Ferdowsi University of Mashhad (FUM), Mashhad, PO Box 917751436, Iran.
Abstract:
The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). Cryst. Struct. Commun. 4, 5-8] of ammonium μ-oxido-μ-[1,5,6-tri-hydroxy-hexane-2,3,4-tris-(olato)]bis-[dioxidomolybdenum(V)] monohydrate, NH4[Mo2(C6H11O6)O5]·H2O, was obtained from an attempt to prepare a glutamic acid complex from the [Co2Mo10H4O38]6- anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds. A Hirshfeld surface analysis was also performed.
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