Highly Reversible Sodiation/Desodiation from a Carbon-Sandwiched SnS₂ Nanosheet Anode for Sodium Ion Batteries

The further improvement of sodium ion batteries requires the elucidation of the mechanisms pertaining to reversibility, which allows the novel design of the electrode structure. Here, through a hydrogel-embedding method, we are able to confine the growth of few-layer SnS₂ nanosheets between a nitrogen- and sulfur-doped carbon nanotube (NS-CNT) and amorphous carbon. The obtained carbon-sandwiched SnS₂ nanosheets demonstrate excellent sodium storage properties. In operando small-angle X-ray scattering combined with the ex situ X-ray absorption near edge spectra reveal that the redox reactions between SnS₂/NS-CNT and the sodium ion are highly reversible. On the contrary, the nanostructure evolution is found to be irreversible, in which the SnS₂ nanosheets collapse, followed by the regeneration of SnS₂ nanoparticles. This work provides operando insights into the chemical environment evolution and structure change of SnS₂-based anodes, elucidating its reversible reaction mechanism, and illustrates the significance of engineered carbon support in ensuring the electrode structure stability.