Screening of chemical composition and risk index of different origin composts produced in Lithuania

The application of composts could be accompanied by potential hazards to soil and humans, caused by heavy metals and organic persistent pollutants. A total of 115 compost samples from four different origins (green waste composts, sewage sludge composts, mixed municipal waste composts after mechanical-biological treatment and mixed municipal waste compost) were collected to analyse the chemical composition, nutrients levels, seven heavy metals, 15 polycyclic aromatic hydrocarbons (PAHs) and seven polychlorobiphenyls (PCBs). Simulation models were used to estimate the heavy metal accumulation risk in soil and to evaluate the potential ecological risk to environment. After analysing chemical parameters of compost quality, it was found that sewage sludge composts contained the highest amounts of nitrogen (2.98%), phosphorus (4.44%) and organic matter (47.6%), and the highest potassium content (1.20%) was found in mixed municipal composts after mechanical-biological treatment. After having tested all the composts, green waste composts had the lowest content of the following nutrients: nitrogen, phosphorus, potassium and sulphur. High molecular weight PAHs dominated in green waste, sewage sludge and mixed municipal waste composts, and the opposite tendency was observed on mixed municipal waste composts after mechanical-biological treatment; low molecular weight PAHs were abundant. It was determined that, according to the total amount of 15 PAHs (16.54 mg kg^-1 d.w.) and 7 PCBs (233.53 μg kg^-1 d.w.), the most contaminated composts were produced from mixed municipal waste. As it was expected, the lowest level of PCBs (13.85 μg kg^-1 d.w.) was found in green waste composts. Monte Carlo simulations showed that the shortest period in which zinc concentration in soil could increase twice is 2 years when applying continuously mixed municipal waste compost after mechanical-biological treatment. Based on Monte Carlo simulation results from repeated application of green waste composts, mixed municipal waste compost and mixed municipal waste compost after mechanical-biological treatment could double the soil background level of copper in 6 and 3 years respectively. Reducing the content of heavy metals in composts would be of great significance for minimising the damage caused by them.